Do two promising structural materials corrode at very high temperatures when in contact with “liquid metal fuel breeders” in fusion reactors? Researchers of Tokyo Institute of Technology (Tokyo Tech), National Institutes for Quantum Science and Technology (QST), and Yokohama National University (YNU) now have the answer. This high-temperature compatibility of reactor structural materials with the liquid breeder—a lining around the reactor core that absorbs and traps the high energy neutrons produced in the plasma inside the reactor—is key to the success of a fusion reactor design.
Fusion reactors could be a powerful means of generating clean electricity, and currently, several potential designs are being explored. In a fusion reactor, the fusion of two nuclei releases massive amounts of energy. This energy is trapped as heat in a “breeding blanket” (BB), typically a liquid lithium alloy, surrounding the reactor core. This heat is then used to run a turbine and generate electricity. The BB also has an essential function of fusion fuel breeding, creating a closed fuel cycle for the endless operation of the reactors without fuel depletion.
The operation of a BB at extremely high temperatures over 1173 K serves the attractive function of producing hydrogen from water, which is a promising technology for realizing a carbon-neutral society. This is possible because the BB heats up to over 1173 K by absorbing the energy from the fusion reaction. At such temperatures, there is the risk of structural materials in contact with the BB becoming corroded, compromising the safety and stability of the reactors. It is thus necessary to find structural materials that are chemically compatible with the BB material at these temperatures.
One type of BB currently being explored is the liquid metal BB. A promising candidate for such BBs is liquid lithium lead (LiPb) alloy. As candidates for structural materials compatible with liquid LiPb at very high temperatures, a certain silicon carbide (SiC) material, CVD-SiC, and an iron-chromium-aluminum (FeCrAl) alloy pre-oxidized in air are being explored. But information on this compatibility is lacking beyond temperatures of 973 K.
Now, a team of scientists from Tokyo Tech, QST and YNU, Japan, led by Professor Masatoshi Kondo from Tokyo Tech, have demonstrated compatibility at much higher temperatures. Their findings are published in Corrosion Science. “Our study makes clear the nuances of the corrosion resistance mechanism of CVD-SiC and FeCrAl alloys in liquid LiPb up to 1173 K,” Prof. Kondo explains.
The team first synthesized high-purity LiPb by melting and mixing granules of Li and Pb in an apparatus under vacuum conditions. They then heated the alloy to the aforementioned temperatures, at which it was liquified. Samples of CVD-SiC and two variants of the FeCrAl alloy—with and without pre-oxidation treatment to form an α-Al2O3surface layer—were placed in this liquid LiPb for 250 hours for corrosion testing. Prof. Kondo observes, “An interesting finding is that contrary to previous literature, oxidation pre-treatment to form an α-Al2O3 layer did not provide corrosion resistance beyond 1023 K.”
Cross-sections of the retrieved samples showed that CVD-SiC reacted with impurities in the LiPb alloy to form a layer of complex oxides, which then provided it with corrosion resistance. The untreated FeCrAl alloy formed a layer of the oxide γ-LiAlO2 upon reaction with LiPb, which then acted as an anti-corrosion barrier. In the case of the pre-treated FeCrAl, the α-Al2O3 surface layer provided corrosion resistance at 873 K but transformed into γ-LiAlO2 at 1173 K, and it was γ-LiAlO2 that then provided corrosion resistance.
Masatoshi Kondo et al, Corrosion-resistant materials for liquid LiPb fusion blanket in elevated temperature operation, Corrosion Science (2021). DOI: 10.1016/j.corsci.2021.110070
Selecting the right structural materials for fusion reactors (2022, March 3)
retrieved 3 March 2022
% %item_read_more_button%% Hexbyte Glen Cove Educational Blog Repost With Backlinks — #metaverse #vr #ar #wordpress
It’s challenging to make predictions, especially in astronomy. There are however, a few forecasts astronomers can depend on, such as the timing of upcoming lunar and solar eclipses and the clockwork return of some comets.
Now, looking far beyond the solar system, astronomers have added a solid prediction of an event happening deep in intergalactic space: an image of an exploding star, dubbed Supernova Requiem, which will appear around the year 2037. Although this rebroadcast will not be visible to the naked eye, some future telescopes should be able to spot it.
It turns out that this future appearance will be the fourth-known view of the same supernova, magnified, brightened, and split into separate images by a massive foreground cluster of galaxies acting like a cosmic zoom lens. Three images of the supernova were first found from archival data taken in 2016 by NASA’s Hubble Space Telescope.
The multiple images are produced by the monster galaxy cluster’s powerful gravity, which distorts and magnifies the light from the supernova far behind it, an effect called gravitational lensing. First predicted by Albert Einstein, this effect is similar to a glass lens bending light to magnify the image of a distant object.
The three lensed supernova images, seen as tiny dots captured in a single Hubble snapshot, represent light from the explosive aftermath. The dots vary in brightness and color, which signify three different phases of the fading blast as it cooled over time.
“This new discovery is the third example of a multiply imaged supernova for which we can actually measure the delay in arrival times,” explained lead researcher Steve Rodney of the University of South Carolina in Columbia. “It is the most distant of the three, and the predicted delay is extraordinarily long. We will be able to come back and see the final arrival, which we predict will be in 2037, plus or minus a couple of years.”
The light that Hubble captured from the cluster, MACS J0138.0-2155, took about four billion years to reach Earth. The light from Supernova Requiem needed an estimated 10 billion years for its journey, based on the distance of its host galaxy.
The team’s prediction of the supernova’s return appearance is based on computer models of the cluster, which describe the various paths the supernova light is taking through the maze of clumpy dark matter in the galactic grouping. Dark matter is an invisible material that comprises the bulk of the universe’s matter and is the scaffolding upon which galaxies and galaxy clusters are built.
Each magnified image takes a different route through the cluster and arrives at Earth at a different time, due, in part, to differences in the length of the pathways the supernova light followed.
“Whenever some light passes near a very massive object, like a galaxy or galaxy cluster, the warping of space-time that Einstein’s theory of general relativity tells us is present for any mass, delays the travel of light around that mass,” Rodney said.
He compares the supernova’s various light paths to several trains that leave a station at the same time, all traveling at the same speed and bound for the same location. Each train, however, takes a different route, and the distance for each route is not the same. Because the trains travel over different track lengths across different terrain, they do not arrive at their destination at the same time.
In addition, the lensed supernova image predicted to appear in 2037 lags behind the other images of the same supernova because its light travels directly through the middle of the cluster, where the densest amount of dark matter resides. The immense mass of the cluster bends the light, producing the longer time delay. “This is the last one to arrive because it’s like the train that has to go deep down into a valley and climb back out again. That’s the slowest kind of trip for light,” Rodney explained.
The lensed supernova images were discovered in 2019 by Gabe Brammer, a study co-author at the Cosmic Dawn Center at the Niels Bohr Institute, University of Copenhagen, in Denmark. Brammer spotted the mirrored supernova images while analyzing distant galaxies magnified by massive foreground galaxy clusters as part of an ongoing Hubble program called REsolved QUIEscent Magnified Galaxies (REQUIEM).
He was comparing new REQUIEM data from 2019 with archival images taken in 2016 from a different Hubble science program. A tiny red object in the 2016 data caught his eye, which he initially thought was a far-flung galaxy. But it had disappeared in the 2019 images.
“But then, on further inspection of the 2016 data, I noticed there were actually three magnified objects, two red and a purple,” he explained. “Each of the three objects was paired with a lensed image of a distant massive galaxy. Immediately it suggested to me that it was not a distant galaxy but actually a transient source in this system that had faded from view in the 2019 images like a light bulb that had been flicked off.”
Brammer teamed up with Rodney to conduct a further analysis of the system. The lensed supernova images are arranged in an arc around the cluster’s core. They appear as small dots near the smeared orange features that are thought to be the magnified snapshots of the supernova’s host galaxy.
Study co-author Johan Richard of the University of Lyon in France produced a map of the amount of dark matter in the cluster, inferred from the lensing it produces. The map shows the predicted locations of lensed objects. This supernova is predicted to appear again in 2042, but it will be so faint that the research team thinks it will not be visible.
Catching the rerun of the explosive event will help astronomers measure the time delays between all four supernova images, which will offer clues to the type of warped-space terrain the exploded star’s light had to cover. Armed with those measurements, researchers can fine-tune the models that map out the cluster’s mass. Developing precise dark-matter maps of massive galaxy clusters is another way for astronomers to measure the universe’s expansion rate and investigate the nature of dark energy, a mysterious form of energy that works against gravity and causes the cosmos to expand at a faster rate.
This time-delay method is valuable because it’s a more direct way of measuring the universe’s expansion rate, Rodney explained. “These long time delays are particularly valuable because you can get a good, precise measurement of that time delay if you are just patient and wait years, in this case more than a decade, for the final image to return,” he said. “It is a completely independent path to calculate the universe’s expansion rate. The real value in the future will be using a larger sample of these to improve the precision.”
Spotting lensed images of supernovae will become increasingly common in the next 20 years with the launch of NASA’s Nancy Grace Roman Space Telescope and the start of operations at the Vera C. Rubin Observatory. Both telescopes will observe large swaths of the sky, which will allow them to spot dozens more multiply imaged supernovae.
Future telescopes such as NASA’s James Webb Space Telescope also could detect light from supernova Requiem at other epochs of the blast. The team’s results will appear on September 13 in the journal Nature Astronomy.
Rerun of supernova blast expected to appear in 2037 (2021, September 13)
retrieved 14 September 2021
This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no
part may be reproduced without the written permission. The content is provided for information purposes only.
Read More Hexbyte Glen Cove Educational Blog Repost With Backlinks —